Field-enhanced photocurrent spectroscopy of excitonic states in single-wall carbon nanotubes.

نویسندگان

  • Aditya Mohite
  • Ji-Tzuoh Lin
  • Gamini Sumanasekera
  • Bruce W Alphenaar
چکیده

Excitonic and free-carrier transitions in single-wall carbon nanotubes are distinguished using field-enhanced photocurrent spectroscopy. Electric field dissociation allows for the detection of bound-exciton states that otherwise would not contribute to the photocurrent. Excitonic states associated with both the ground-state semiconductor and the ground-state metallic nanotube transitions are resolved. The observation of a metallic excitonic state corroborates recent predictions of a symmetry gap existing in metallic nanotubes.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Strain tuning of the photocurrent spectrum in single-wall carbon nanotubes.

The effect of uniaxial strain on the photocurrent spectrum of semiconducting single-wall carbon nanotubes is measured. The energy of the lowest-lying free electron transition is observed to shift with strain as predicted by a simple noninteracting model. The higher-order transitions also shift with strain, but being excitonic, their strain dependence differs from the predictions for the free ca...

متن کامل

Photoexcitation of the triplet exciton in single wall carbon nanotubes

The carbon nanotube photoexcitation spectrum is dominated by excitonic transitions, rather than interband transitions between continuum states. There are eight distinct excitonic transitions (four singlet and four triplet), each with two-fold degeneracy. Because the triplet excitons are spin polarized with electron and hole spins both pointing in the same direction, they are optically inactive,...

متن کامل

Exciton dissociation and stark effect in the carbon nanotube photocurrent spectrum.

The field-dependent photocurrent spectrum of individual carbon nanotubes is measured using a displacement photocurrent technique. A series of peaks is observed in the photocurrent corresponding to both excitonic and free carrier transitions. The photocurrent peak corresponding to the ground state exciton increases by a factor of 200 beyond a critical electric field, and shows both red and blue ...

متن کامل

Photocurrent spectroscopy of exciton and free particle optical transitions in suspended carbon nanotube pn-junctions

Articles you may be interested in Single carbon nanotube photovoltaic device Scanning photocurrent and photoluminescence imaging of a frozen polymer p-n junction Appl. Large-signal and high-frequency analysis of nonuniformly doped or shaped pn-junction diodes Direct probe of excitonic and continuum transitions in the photocurrent spectroscopy of individual carbon nanotube p-n diodes Appl.

متن کامل

Direct observation of dark excitons in micelle-wrapped single-wall carbon nanotubes.

We have performed electroabsorption spectroscopy on micelle-wrapped single-wall carbon nanotubes. In semiconducting nanotubes, many oscillating structures composed of the increase and decrease of absorption are observed in the spectra in the region of the first and second absorption bands, E11 and E22. The spectral shape is reproduced mainly by the second-derivative curve of the absorption spec...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Nano letters

دوره 6 7  شماره 

صفحات  -

تاریخ انتشار 2006